Some diphosphine complexes of tungsten-(III) and -(IV)
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2466-2467
- https://doi.org/10.1039/j19680002466
Abstract
The preparation of several complexes of tungsten-(III) and -(IV) with 1,2-bisdiphenylphosphinoethane (diphos) is described. On the basis of analytical data, far-infrared spectra, magnetic measurements, and, where appropriate, electrical conductivity and molecular weight measurements, the complexes are formulated as [WCl3diphos]2, [WCl3(diphos)2], [WCl2(diphos)2]+Cl–, [WCl4diphos], and [WCl2(diphos)2]2+[WCl6]2–.Keywords
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