Notizen: Die Umylidierungsreaktion von Zirkoniumtetrachlorid mit Phosphonium-yliden: Struktur von Methyl-tris(diethylamino)- phosphonium-Hexachlorozirkonat / The Transylidation Reaction of Zirconium tetrachloride with Phosphonium Ylides: Structure of Methyl-tris(diethylamino)- phosphonium Hexachlorozirconate
Open Access
- 1 March 1986
- journal article
- research article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 41 (3) , 395-398
- https://doi.org/10.1515/znb-1986-0318
Abstract
The reaction between ZrCl4 and (Et2N)3P=CH2 affords the zirconium-substituted vlide [(Et2N)3PCZrCl2]2 (1). The transylidation by-product [(Et2N)3PCH3]Cl is trapped by excess ZrCl4 to give the complex salt [(Et2N)3PCH3]2ZrCl6 (2) the structure of which was determined by single crystal X-ray diffraction.Keywords
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