Stereoselective photochemical ring-opening of cyclohexa-2,4-dienones
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- p. 3274-3280
- https://doi.org/10.1039/j39710003274
Abstract
The stereoselectivity of the photochemical ring-opening of 6-acetoxy-6-methylcyclohexa-2,4-dienones to derivatives of hepta-3,5-dienoic acid has been shown to be general, and the stereochemistry of the products has been studied by use of n.m.r. long-range coupling and solvent-shift data. Two representative 6-benzoyloxy-analogues behave in a similar manner.Keywords
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