Statistical-Mechanical Properties of Small Systems in the Isothermal—Isobaric Ensemble
- 15 April 1966
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 44 (8) , 3090-3094
- https://doi.org/10.1063/1.1727184
Abstract
The exact N dependence is given for the first N − 1 virial coefficients calculated for a system with a finite number, N, of particles in the isobaric‐isothermal ensemble. When the specific volume v=V/(N+1) is expanded as a power series in z=p/kT, it is shown that the first N − 1 coefficients are linear functions of (N+1)−1. The explicit results are given for the first six coefficients.Keywords
This publication has 6 references indexed in Scilit:
- Fifth and Sixth Virial Coefficients for Hard Spheres and Hard DisksThe Journal of Chemical Physics, 1964
- Thermodynamic Properties of Small SystemsPhysical Review B, 1961
- Studies in Molecular Dynamics. II. Behavior of a Small Number of Elastic SpheresThe Journal of Chemical Physics, 1960
- Density expansions of distribution functions. I.: Virial expansion for finite closed systems: Canonical esemblePhysica, 1957
- Pressure Virial Coefficients in Terms of Cluster IntegralsThe Journal of Chemical Physics, 1953
- On the theory of condensationPhysica, 1938