Resolution of Alcohols as Esters by HPLC on (+)-Poly(triphenylmethyl methacrylate)
- 1 October 1985
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 58 (10) , 3053-3054
- https://doi.org/10.1246/bcsj.58.3053
Abstract
Various secondary alcohols were resolved as benzoates or 3,5-dichlorobenzoates by high-performance liquid chromatography on optically active (+)-poly(triphenylmethyl methacrylate). Almost completely resolved alcohols include 2-butanol, 2-pentanol, 2-octanol, 3-octanol, 1-phenylethanol, cis-2-methylcyclohexanol, trans- and cis-3-methyl-cyclohexanol, and tetrahydrofurfuryl alcohol.Keywords
This publication has 18 references indexed in Scilit:
- Chromatographic resolution. 7. Useful chiral packing materials for high-performance liquid chromatographic resolution of enantiomers: phenylcarbamates of polysaccharides coated on silica gelJournal of the American Chemical Society, 1984
- Structure ofTetrahedron Letters, 1983
- Stereoisomerism in molecular bevel-gears. Optical resolution of the DL isomers of bis(2- and 3-chloro-9-triptycyl)methanes and ethersTetrahedron Letters, 1983
- Synthesis and optical resolution of 4,6-dideoxy-3,5-O-isopropylidene-2-O-(methoxymethyl)-DL-glucitol.CHEMICAL & PHARMACEUTICAL BULLETIN, 1983
- Preparation and structure of (Tetrahedron Letters, 1982
- Novel packing material for optical resolution: (+)-poly(triphenylmethyl methacrylate) coated on macroporous silica gelJournal of the American Chemical Society, 1981
- Preparation of (-)-(M)-[2.2]paracyclophanohexahelicene from (-)-(M)-1,4-dimethylhexahelicene and the absolute configuration of 4-substituted [2.2]paracyclophanesThe Journal of Organic Chemistry, 1981
- Asymmetric polymerization of triphenylmethyl methacrylate by optically active anionic catalystsJournal of Polymer Science: Polymer Chemistry Edition, 1980
- Resolution of racemic compounds by optically active poly(triphenylmethyl methacrylate)Journal of the American Chemical Society, 1980
- Optically active poly(triphenylmethyl methacrylate) with one-handed helical conformationJournal of the American Chemical Society, 1979