Chemistry of Silylketene: A One-Pot Synthesis of α-Silyl Ketones
- 1 January 1991
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1991 (06) , 401-402
- https://doi.org/10.1055/s-1991-20741
Abstract
Addition of organocerium reagents 4 prepared from cerium(III) chloride and an alkyl- or aryllithium, to silylketenes 3a-c and the subsequent quenching with aqueous ammonium chloride or alkyl halides 5 gives the corresponding α-silyl ketones 1 in 53-99% yield.Keywords
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