Standard Chemical Thermodynamic Properties of Alkene Isomer Groups

Publisher Website
Google Scholar
Abstract
The chemical thermodynamic properties of alkene isomer groups from C4H8 to C6H12 in the ideal gas phase have been calculated from 298.15 to 1000 K from tables of Stull, Westrum, and Sinke. In the absence of literature data on all isomers of higher isomer groups, the properties of isomers of C7H14 to C8H16 have been estimated using Benson group values. Equilibrium mole fractions within isomer groups have been calculated for the ideal gas state from 298.15 to 1000 K. For isomer group properties increments per carbon atom have been calculated to show the extent to which thermodynamic properties of higher isomer groups may be obtained by linear extrapolation. Values of C○P, S°, ΔfH°, and ΔfG° are given for all species from C2H4 to C8H16 in joules for a standard state pressure of 1 bar.

This publication has 0 references indexed in Scilit: