Reactions of carbodi-imides with palladium(II) compounds
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 18,p. 1867-1870
- https://doi.org/10.1039/dt9730001867
Abstract
New dihalogenobis(carbodi-imide)palladium(II) compounds are formed in the reactions between di-t-butyl- and methyl-t-butylcarbodi-imides and (PhCN)2PdX2(X = Cl and Br) in dichloromethane solution. In methanol solution, 1,2-addition of solvent to di-o-tolyl-, dicyclohexyl- and methyl-t-butylcarbodi-imides is promoted by PdII, and dihalogenobis(isourea) complexes are obtained. Structures of the compounds are discussed on the basis of i.r. and 1H n.m.r. observations.Keywords
This publication has 0 references indexed in Scilit: