Phosphodiester bond cleavage mediated by a cyclic β-sheet peptide-based dinuclear zinc(ii) complex
- 28 June 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 14,p. 1315-1316
- https://doi.org/10.1039/b003370g
Abstract
A dinuclear Zn(II) complex of N2δ,N2δ,N 2′δ,N2′δ-tetra kis(2-pyridylmethyl) derivative of cyclic peptide gramicidin S markedly accelerated the cleavage of the phosphodiester linkage of the RNA model substrate 2-hydroxypropyl p-nitrophenyl phosphate.Keywords
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