Kinetic Isotope Effects for Acyl Transfer from p-Nitrophenyl Acetate to Hydroxylamine Show a pH-Dependent Change in Mechanism
- 1 July 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 119 (30) , 6980-6983
- https://doi.org/10.1021/ja970648k
Abstract
No abstract availableThis publication has 8 references indexed in Scilit:
- Heavy-atom isotope effects on the alkaline hydrolysis of methyl formate: the role of hydroxide ion in ester hydrolysisJournal of the American Chemical Society, 1993
- Concertedness in acyl group transfer in solution: a single transition state in acetyl group transfer between phenolate ion nucleophilesJournal of the American Chemical Society, 1987
- Conformational and structural analysis of methyl hydrazinocarboxylate by microwave spectroscopy and ab initio geometry refinementsJournal of the American Chemical Society, 1986
- Bifurcated hydrogen bond and large amplitude vibrations in glycine methyl esterJournal of the American Chemical Society, 1982
- p.pi.p.pi. Interactions in organic molecules. 3. Theoretical search for a new nonclassical carbonium ion: the .sigma.-allyl cationJournal of the American Chemical Society, 1980
- Nonlinear structure-reactivity correlations. Acyl transfer between sulfur and oxygen nucleophilesJournal of the American Chemical Society, 1977
- Mechanism of partitioning of the intermediates formed in the hydrolysis of phenyl imidatesJournal of the American Chemical Society, 1974
- Reactions of Amines. III. Pyrolysis of N-Alkylacetamides1,2Journal of the American Chemical Society, 1958