Electronic decay of vibrationally selected core excited states in molecular N2
- 1 August 1993
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 99 (3) , 1633-1636
- https://doi.org/10.1063/1.465332
Abstract
We have measured and analyzed the vibrational fine structure of the electronic participator decay of the 1s −11π g state in gas‐phase N2. The monochromator resolution allowed us to limit the vibrational excitations in the excited state so that unequivocally assignable vibrational fine structure in the decay spectra could be resolved. The excitation‐emission process is shown to be well‐described within the two‐step Franck–Condon model, and the data represents individual decay of vibrationally selected core excited states.Keywords
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