Enantiomeric differentiation by chiral macrocyclic polyethers derived from D-mannitol and binaphthol

1 January 1976

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 8,p. 284-285
https://doi.org/10.1039/c39760000284

Abstract

The chiral macrocyclic polyethers (R)-D-(5) and (S)-D-(5) derived from D-mannitol and (R)- and (S)- binaphthol respectively exhibit comparable enantiomeric selectivities in complexing (±)-(RS)-α-phenylethylammonium hexafluorophosphate under equilibrium conditions.

Keywords

DIFFERENTIATION
ENANTIOMERIC
CHIRAL MACROCYCLIC
POLYETHERS
HEXAFLUOROPHOSPHATE
PHENYLETHYLAMMONIUM