Hydrolysis of magnesium(II) in 1.0 mol dm–3aqueous (Na,H)NO3solution
- 1 January 1977
- journal article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 9,p. 912-914
- https://doi.org/10.1039/dt9770000912
Abstract
Hydrolysis of magnesium(II) has been studied in 1.0 mol dm–3(Na,H)NO3 aqueous solution at 25.0 °C by means of e.m.f. measurements of a cell containing suitable test solutions. Magnesium(II) is hydrolyzed to form polynuclear complexes [Mg2(OH)2]2+(log β22–22.07) and [Mg3(OH)4]2+(log β34–39.06). The formation of these species can be accounted for by the ‘truncated-core-plus-links’ expression.Keywords
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