Reductive cleavage and related reactions leading to molybdenum–element multiple bonds: new pathways offered by three-coordinate molybdenum(III)
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 17,p. 1777-1786
- https://doi.org/10.1039/a802402b
Abstract
Three-coordinate molybdenum(III) complexes comprise a new class of reactive-yet-isolable substances. Related to a well known class of metal–metal triple bonded dimers, the monomeric molybdenum(III) complexes supported by sterically-demanding N-tert-alkylanilide ligands offer previously unavailable synthetic routes to molybdenum–element multiple bonds. Terminal nitride, phosphide and carbide functionalities have been prepared from reactions with dinitrogen, white phosphorus and carbon monoxide, respectively.This publication has 7 references indexed in Scilit:
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