Lewis acid assisted annelation of trimethylsilyl enol ethers of 1-acetylcyclohexenes with α,β-unsaturated carbonyl compounds to give substituted 2-decalones; synthesis of (±)-ε-cadinene
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1333-1335
- https://doi.org/10.1039/c39870001333
Abstract
The trimethylsilyl enol ethers of 1-acetylcyclohexenes undergo a Lewis-acid-assisted one-pot annelation reaction with α,β-unsaturated carbonyl compounds to produce 5-substituted 2-decalones; the application of this reaction has enabled a synthesis of (±)-ε-cadinene (12).Keywords
This publication has 0 references indexed in Scilit: