Probing the Magnetic Anisotropy of Lanthanide‐Containing Metallomesogens by Luminescence Spectroscopy
- 16 November 2001
- journal article
- Published by Wiley in Chemphyschem
- Vol. 2 (11) , 680-683
- https://doi.org/10.1002/1439-7641(20011119)2:11<680::aid-cphc680>3.0.co;2-#
Abstract
The alignment of liquid crystals through magnetism demands a high value of the magnetic anisotropy. The magnitude of the anisotropy for a series of isostructural lanthanide-containing metallomesogens can be estimated on basis of the crystal-field splitting of the (7)F1 multiplet in the corresponding europium(III) compounds. A method to rapidly measure this splitting value is accessible through photoluminescence measurements.Keywords
This publication has 20 references indexed in Scilit:
- Magnetic anisotropy of the smectic A phases of lanthanide complexes derived from Schiff's bases and DOS, NO 3 anionsLiquid Crystals, 2001
- On the magnetic anisotropy of lanthanide-containing metallomesogensThe Journal of Chemical Physics, 2000
- Rare-Earth-Containing Magnetic Liquid CrystalsJournal of the American Chemical Society, 2000
- Synthesis and Magnetic Investigations on Rare-Earth-Containing Liquid Crystals with Large Magnetic AnisotropyChemistry of Materials, 1996
- Paramagnetic smectic liquid crystals: synthesis and properties of bis(N-aryl-4-[(4'-decyloxy)benzyloxy]salicylaldimine)copper(II) and oxovanadium(IV)Chemistry of Materials, 1993
- X-ray diffraction study of some mesogenic copper, nickel and vanadyl complexesLiquid Crystals, 1991
- Liquid-crystalline complexes of rare-earth elements with a Shiff baseRussian Chemical Bulletin, 1991
- Metallomesogens: Metal Complexes in Organized Fluid PhasesAngewandte Chemie International Edition in English, 1991
- Metallomesogene: Metallkomplexe in geordneten fluiden PhasenAngewandte Chemie, 1991
- Liquid crystal complexes of copper with Schiff basesRussian Chemical Bulletin, 1984