The Analysis of the Infrared Spectrum of Chlorine Monofluoride

Abstract
The vibration‐rotation fine‐structure of the fundamental and first overtone of ClF has been resolved with grating spectrometers utilizing an 1800 lines‐per‐inch and a 3600 lines‐per‐inch grating. An analysis of the observed bands is given and the ωe and xeωe for Cl35F19 and Cl37F19 were found to be 786.34 cm−1, 6.23 cm−1, and 778.82 cm−1, and 6.11 cm−1, respectively.

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