Preparation and Ring-Opening Reactions of N-Diphenylphosphinyl Vinyl Aziridines
Open Access
- 1 September 1996
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1996 (09) , 847-849
- https://doi.org/10.1055/s-1996-5605
Abstract
N-Diphenylphosphinyl-3-ethenyl-2-phenylaziridine (1) and N-diphenylphosphinyl-3-ethenyl-2-(4-bromophenyl)aziridine (2) are prepared by reaction of α-bromo allyllithium with N-diphenylphosphinyl aldimines in the presence of zinc chloride. (1) and (2) undergo efficient SN2’ ring-opening reaction with several nucleophiles.Keywords
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