Hydrido-bridged complexes of gold and silver: X-ray crystal structure of [AuCr(µ-H)(CO)5(PPh3)]
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 813-814
- https://doi.org/10.1039/c39820000813
Abstract
The compounds [MM′(µ-H)(CO)5(PR3)](M = Cr,Mo or W,M′= Au, R = Ph;M = Cr or W. M = Ag R = Me) have been prepared by treating [AuCl(PPh3)] or [Agl(PMe3]with [Ph3P)2N][MH(CO)5](M = Cr or W) or [Ph3P)2N][Mo2(µ-H)(co)10] in the presence of TlPF6; the structure of [AuCr(µ-H)(CO)5)PPh3)] has been established by X-ray crystallography.Keywords
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