Chemical Decomposition of Chlorofluorocarbons by Reductive Dehalogenation Using Sodium Naphthalenide
- 5 October 1988
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 17 (10) , 1789-1792
- https://doi.org/10.1246/cl.1988.1789
Abstract
All halogen atoms in 1,1,2-trichloro-1,2,2-trifluoroethane (F-113) were removed in the form of chloride and fluoride ions by the treatment with sodium naphthalenide (1.5 equiv. per halogen atom) in THF at 150 °C for 50 min in the presence of 10 vol% tetraethyleneglycol dimethylether. Similar treatment was also efficacious in the dehalogenation of F-22 and F-12.This publication has 4 references indexed in Scilit:
- Formation of polychlorinated dibenzo‐p‐dioxins (PCDDS) and dibenzofurans (PCDFS) in typical urban incinerators in JapanToxicological & Environmental Chemistry, 1988
- Nonhomogeneous phase effect on the generation of carbene radical anions in the Birch-type reduction of bis(gem-dihalocyclopropyl)compoundsThe Journal of Organic Chemistry, 1983
- Conducting Polymer Prepared from TeflonJapanese Journal of Applied Physics, 1982
- Reactions of the radical anions and dianions of aromatic hydrocarbonsChemical Reviews, 1974