Synthesis of Elastomeric Poly(propylene) Using Unsymmetrical Zirconocene Catalysts: Marked Reactivity Differences of “Rac”- and “Meso”-like Diastereomers
- 1 February 1998
- journal article
- research article
- Published by American Chemical Society (ACS) in Macromolecules
- Vol. 31 (4) , 1000-1009
- https://doi.org/10.1021/ma971325b
Abstract
No abstract availableKeywords
This publication has 32 references indexed in Scilit:
- Efficient Synthesis of rac-(Ethylenebis(indenyl))ZrX2 Complexes via Amine EliminationOrganometallics, 1995
- Density Functional Study of the Insertion Step in Olefin Polymerization by Metallocene and Constrained-Geometry CatalystsOrganometallics, 1994
- Ethylidene(1-.eta.5-tetramethylcyclopentadienyl)(1-.eta.5-indenyl)dichlorozirconium: synthesis, molecular structure, and polymerization catalysisOrganometallics, 1993
- Metallocene catalysts for olefin polymerizations. XXIV. Stereoblock propylene polymerization catalyzed by rac‐[anti‐ethylidene(1‐η5‐tetramethylcyclopentadienyl)(1‐η5‐indenyl)dimethyltitanium: A two‐state propagationJournal of Polymer Science Part A: Polymer Chemistry, 1992
- Two-state propagation mechanism for propylene polymerization catalyzed by rac-[anti-ethylidene(1-.eta.5-tetramethylcyclopentadienyl)(1-.eta.5-indenyl)] dimethyltitaniumJournal of the American Chemical Society, 1991
- rac-[Ethylidene(1-.eta.5-tetramethylcyclopentadienyl)(1-.eta.5-indenyl)]dichlorotitanium and its homopolymerization of propylene to crystalline-amorphous block thermoplastic elastomersJournal of the American Chemical Society, 1990
- Elastomeric polypropylenes from alumina-supported tetraalkyl group IVB catalysts. 2. Chain microstructure, crystallinity, and morphologyMacromolecules, 1989
- Elastomeric polypropylenes from alumina-supported tetraalkyl Group IVB catalysts. 1. Synthesis and properties of high molecular weight stereoblock homopolymersMacromolecules, 1989
- Microstructure of isotactic polypropylene prepared with homogeneous catalysis: stereoregularity, regioregularity, and 1,3 insertionMacromolecules, 1988
- Properties of isotactic, atactic, and stereoblock homopolymers, random and block copolymers of α‐olefinsJournal of Polymer Science, 1959