An investigation of the kinetics of a reversible monomolecular reaction between n components
- 1 January 1979
- journal article
- Published by Institute of Organic Chemistry & Biochemistry in Collection of Czechoslovak Chemical Communications
- Vol. 44 (4) , 1146-1159
- https://doi.org/10.1135/cccc19791146
Abstract
It has been shown that the solution of kinetic equations can be transformed into diagonalization of a symmetrical matrix, in contrast with the solution known so far and requiring diagonalization of a nonsymmetrical matrix. Simple formulas are given for the calculation of derivatives of the concentrations of individual components with respect to the parameters. All formulas are presented in a compact matrix form; their uniformity for a large number of cases recognized in the existing literature greatly facilitates writing computer programs for calculations of reaction kinetics.Keywords
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