Radikalische Addition an cyclische Derivate der Maleinsäure
- 1 May 1982
- journal article
- organische chemie
- Published by Wiley in European Journal of Inorganic Chemistry
- Vol. 115 (5) , 2012-2014
- https://doi.org/10.1002/cber.19821150533
Abstract
Radical Addition to Cyclic Derivatives of Maleic AcidReactions of cyclohexylmercury acetate (1) with NaBH4 in the presence of cyclic alkenes 4 yield the products 5 in high yields (Tab. 1). The main step of the reaction sequence is the addition of a cyclohexyl radical to the alkene 4. The rate of the addition increases with increasing electron withdrawing ability of X (Tab. 1).Keywords
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