Role of Triad Concentration in Glass Transition Temperatures of Copolymers. II
- 1 November 1975
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 9 (7) , 1281-1287
- https://doi.org/10.1080/10601327508056937
Abstract
Improved correlation between glass transition temperatures and copolymer composition was obtained in styrene-methyl methacrylate copolymers by assessing contributions of triad rather than diad concentrations. Contributions of ABA and BAB triads were found to be significantly different. Glass transition temperature minima as a function of copolymer composition were found to be related to the solubility parameters (and cohesive energy densities) of the parent homopolymers.Keywords
This publication has 3 references indexed in Scilit:
- Role of Triad Concentration in Glass Transition Temperatures of CopolymersJournal of Macromolecular Science: Part A - Chemistry, 1975
- Relation of glass transition temperature to molecular structure of addition copolymersJournal of Polymer Science Part C: Polymer Symposia, 1970
- Physical properties of vinyl polymers. Part 4.—Glass-transition temperature of methyl methacrylate + styrene copolymersTransactions of the Faraday Society, 1962