Evidence for cis- and trans-1,2,3-triphenylaziridine from the ring-opened azomethine ylides
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 19,p. 1188-1190
- https://doi.org/10.1039/c29710001188
Abstract
cis-1,2,3-Triphenylaziridine equilibrates at 150° with the trans-isomer until a 78 : 22 mixture is attained.; the configurational assignments are based on the conrotatory ring-openings to azomethine ylides which were intercepted by suitable dipolarophiles.Keywords
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