N.m.r. studies of tin(IV) porphyrins: evidence for ‘through-space’13C–1H coupling in dihydroxo-5,10,15,20-tetraphenylporphyrinatotin(IV)

Abstract
1 H and 13C N.m.r. spectra of the title compound are reported, the latter showing unusual 13C–1H residual couplings which are rationalized by ‘through-space’ interactions between the Centrally co-ordinated hydroxy hydrogen and porphyrin carbon nuclei.

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