New catalysts for the aerobic selective oxidation of hydrocarbons: Mn(III)- and Co(III)-containing molecular sieves for the epoxidation of alkenes

1 January 1999

journal article
research article
Published by Royal Society of Chemistry (RSC) in Chemical Communications

No. 9,p. 829-830
https://doi.org/10.1039/a901127g

Abstract

Co(III) or Mn(III) ions that replace some 4 atom% of Al(III) sites in microporous aluminophosphate number 36 (AlPO-36) function as catalytically active centres for the production from benzaldehyde of acylperoxy radicals: these, in turn, in dry air (30 bar) convert cyclohexene, pinene, limonene and styrene to their corresponding epoxides and diols.

Keywords

FUNCTION
III
CATALYTICALLY ACTIVE
MOLECULAR SIEVES
CONVERT CYCLOHEXENE
SELECTIVE OXIDATION
AEROBIC SELECTIVE
ACYLPEROXY RADICALS
ALUMINOPHOSPHATE NUMBER

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