A significant effect of anion binding ureas on the product ratio in the palladium(ii)-catalyzed hydrocarbonylation of alkenes
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 23,p. 2613-2614
- https://doi.org/10.1039/a806722h
Abstract
Hydrogen bonding of urea derivatives to the anionic ligands X of (dppp)PdX2 catalysts significantly increases the hydroacylation of cyclopentene relative to the hydroformylation, most probably due to a decreased coordination strength of the anionic ligands.Keywords
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