Palladium on Carbon Encapsulated in POEPOP1500: A Resin-Supported Catalyst for Hydrogenation Reactions
- 11 December 2001
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 4 (1) , 27-30
- https://doi.org/10.1021/ol016812x
Abstract
A new a versatile catalyst for hydrogenation reactions wherein palladium on carbon is encapsulated in POEPOP1500-resin is described. This polymer-supported catalyst has been successfully used in solution phase hydrogenation of a double and a triple bond as well as hydrogenolysis of a benzyl-protecting group. While the activity of the new catalyst is marginally lower than standard 10% Pd/C, it has the advantage of being reused several times without significant loss of reactivity.Keywords
This publication has 7 references indexed in Scilit:
- Size-Selective Hydrogenation of Olefins by Dendrimer-Encapsulated Palladium NanoparticlesJournal of the American Chemical Society, 2001
- Surfactant Mediated Cationic and Anionic Suspension Polymerization of PEG-Based Resins in Silicon Oil: Beaded SPOCC 1500 and POEPOP 1500Journal of Combinatorial Chemistry, 2000
- Activity Enhancement by the Support in the Hydrogenation of C=C Bonds over Polymer-Supported Palladium CatalystsChemistry – A European Journal, 2000
- Physical Properties of Poly(ethylene glycol) (PEG)-Based Resins for Combinatorial Solid Phase Organic Chemistry: A Comparison of PEG-Cross-Linked and PEG-Grafted ResinsJournal of Combinatorial Chemistry, 2000
- Hydrogenation of olefins over palladium(II) complexes supported on a modified macroporous polymer beadPolymer International, 1997
- POEPOP and POEPS: Inert polyethylene glycol crosslinked polymeric supports for solid synthesisTetrahedron Letters, 1996
- Synthesis, characterization and biocompatibility of PEGA resinsJournal of Peptide Science, 1995