RHODIUM-CATALYZED AZACARBONYLATION OF ALLYL PHOSPHATES. THE PREPARATION OF β,γ-UNSATURATED AMIDES FROM ALLYL ALCOHOLS
- 5 October 1985
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 14 (10) , 1477-1480
- https://doi.org/10.1246/cl.1985.1477
Abstract
Allyl phosphates undergo a smooth azacarbonylation reaction with amines to afford β,γ-unsaturated amides at 50 °C under CO atmosphere (20 atm) in the presence of Rh6(CO)16 catalyst and Bu4NCl co-catalyst.This publication has 6 references indexed in Scilit:
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