Vibrational spectra and metal–metal bonding in the hexahalogenodigallate(II) ions, Ga2X62–(X = Cl, Br, and I)
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 9,p. 988-991
- https://doi.org/10.1039/dt9730000988
Abstract
The title ions have been prepared as tetra-alkylammonium salts and their i.r. and Raman spectra are reported and assigned according to D3d symmetry. Normal-co-ordinate calculations have been made for Ga2Cl6 2– which indicate a Ga–Ga force constant of 217 N m–1.Keywords
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