Controlled-Release NPK Fertilizer Encapsulated by Polymeric Membranes
- 7 December 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of Agricultural and Food Chemistry
- Vol. 51 (2) , 413-417
- https://doi.org/10.1021/jf020800o
Abstract
The commercial granular fertilizer NPK6-20-30 was coated using polysulfone (PSF), polyacrylonitrile (PAN), and cellulose acetate (CA). The coatings were formed from the polymer solutions by the phase inversion technique. Measurements of the thickness and porosity of the prepared coatings and a microphotographic observation of the coatings were performed. The physical properties of the coatings influence the release rate of macronutrients which are present in the core of the coated fertilizer. In the case of PAN coating with 60.45% porosity, prepared from a 16% polymer solution, 100% of NH4+ and P2O5 was released after 4 h of test and 99.7% of K+ after 5 h of test, whereas in the case of coating with 48.8% porosity, 31.8% of NH4+, 16.7% of P2O5, and 11.6% of K+ was released after 5 h. In all experiments, different selectivities of the coatings in terms of the release of components were observed. The release of potassium through the coatings made of PSF and PAN was the slowest. The same tendency was observed for the release of nitrogen through a coating of CA. The release of fertilizer active components was the slowest in the case of PSF. The lowest porosity coating was prepared from the 18% PSF solution. Keywords: Polymer-coated fertilizer; controlled-release fertilizer; slow-release fertilizerKeywords
This publication has 4 references indexed in Scilit:
- Use of Polysulfone in Controlled-Release NPK Fertilizer FormulationsJournal of Agricultural and Food Chemistry, 2002
- Ultrafiltration and Microfiltration HandbookPublished by Taylor & Francis ,1998
- Polysulfones and their derivatives: Materials for membranes for different separation operationsJournal of Applied Polymer Science, 1991
- Prediction of critical temperature and pressure of organic compounds by group contributionIndustrial & Engineering Chemistry Research, 1989