Deuterium relaxation of chloroform dissolved in a nematic liquid crystal
- 1 May 1977
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 66 (9) , 4018-4024
- https://doi.org/10.1063/1.434455
Abstract
The deuterium relaxation of CDCl3 dissolved in a thermotropic nematic liquid crystal has been studied at 13.0°C and analyzed in the framework of Redfield theory. From the results of a selective Carr–Purcell experiment, a nonselective and two selective inversion ‐ recovery measurements, spectral densities of motion at ω=0, ω=ω0, and ω=2ω0 have been determined, and the results are discussed in relation to present theories for relaxation of solutes in ordered media.Keywords
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