Skeletal characterisation of high nuclearity osmium carbonyl clusters by extended X-ray absorption fine structure (EXAFS) spectroscopy
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 777-779
- https://doi.org/10.1039/c39830000777
Abstract
Non-bonded osmium–osmium distances have been identified from the EXAFS of the Os L(III) edge spectra of Os6(CO)18, [N(PPh3)2]2[Os6(CO)18], and [N(PPh3)2]2[Os10C(CO)24] and can be used to characterise the cluster skeleton.Keywords
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