Synthesis and reactivity of a novel unsaturated dimanganese hydride complex, [Mn2H2(CO)6{(OEt)2POP(OEt)2}]. X-Ray Structure of [Mn4Cu2H6(CO)12{(OEt)2-POP(OEt)2}2]
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1505-1507
- https://doi.org/10.1039/c39850001505
Abstract
The synthesis of [Mn2H2(CO)6{(OEt)2POP(OEt)2}] and its reactions with tetrahydrothiophene, methyl-triphenylphosphinegold(I), sodium amalgam followed by triphenylphosphine–group 1b metal cations, and with copper(I) haliders are described; the structure of [Mn4Cu2H6(CO)12{(OEt)2-POP(OEt)2}2] has been established by X-ray diffraction.Keywords
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