A Highly Regio- and Chemoselective Ring Opening of Epoxides with Trimethylsilyl Azide/Aluminum Isopropoxide

1 January 1988

journal article
research article
Published by Georg Thieme Verlag KG in Synthesis

Vol. 1988 (07) , 541-544
https://doi.org/10.1055/s-1988-27631

Abstract

Functionalized epoxides are regioselectively opened using trimethylsilyl azide/aluminum isopropoxide giving 2-trimethylsiloxy azides by attack on the less substituted carbon.

Keywords

FUNCTIONALIZED
CHEMOSELECTIVE
GIVING
SUBSTITUTED
TRIMETHYLSILOXY
AZIDES
REGIOSELECTIVELY
ATTACK
EPOXIDES

This publication has 0 references indexed in Scilit: