Asymmetric synthesis in carbon–carbon bond forming reactions of α-diazoketones catalysed by homochiral rhodium(II) carboxylates
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 361-362
- https://doi.org/10.1039/c39900000361
Abstract
Partial asymmetric synthesis has been observed in intramolecular C–H insertion, aromatic cycloaddition, and cyclopropanation reactions of α-diazoketones catalysed by homochiral rhodium(II) mandelate and rhodium(II) carboxylates derived from L-proline.Keywords
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