The preparation and crystal structures of platinum stacking compounds containing the S2N2H? ligand: [Pt(S2N2H)(PMe3)2][PF6] and [Pt(S2N2H)(PMe2Ph)2][BF4]
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 711-713
- https://doi.org/10.1039/c39860000711
Abstract
Reaction of cis-PtCl2(PMe3)2 with [Me2Sn(S2N2)]2 and [NH4][PF6] in dichloromethane gives [Pt(S2N2H)(PMe3)2][PF6], (1), or alternatively protonation of [Pt(S2N2)(PMe2Ph)2] yields [Pt(S2N2H)(PMe2Ph)2][BF4],(2); the crystal structures of (1) and (2) reveal that the planar cations stack with significant close interactions.Keywords
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