Selective formation of chiral glycerol ethers: A synthesis of intermediates of a platelet-activating factor (C18-PAF).

1 January 1984

journal article
Published by Pharmaceutical Society of Japan in CHEMICAL & PHARMACEUTICAL BULLETIN

Vol. 32 (2) , 791-794
https://doi.org/10.1248/cpb.32.791

Abstract

Some chiral glycerol ethers serving as key synthetic intermediates of platelet-activating factors (PAF) have been prepared in a selective manner from the acetals, obtained from chiral glycerol derivatives, employing the reductive cleavage reaction of the acetal bond with diisobutylaluminum hydride.

Keywords

CLEAVAGE
C18
HYDRIDE
SERVING
DIISOBUTYLALUMINUM
CHIRAL GLYCEROL
GLYCEROL ETHERS

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