Electronic Spectra and Structure of Sulfur Compounds

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Abstract
The lower‐energy electronic states of a series of saturated sulfur compounds have been investigated theoretically and experimentally. The compounds investigated fell into two categories: the monosulfide series ABS in which the substituents A and B were varied, and the polysulfide series R2S n , where n=1, 2, 3, and 4 and where R was usually CH3. The data collected included ultraviolet vapor spectra, solution spectra,solvent shifts, and vibrational data. Computations followed an approach related to that of Wolfsberg and Helmholz. This theoretical method closely approximates the experimentally observed energies in the compounds containing a single sulfur atom but encounters difficulties when two or more sulfurs are present because of the large 3d S−3d S and 4s S−4s S interactions which are predicted. It is indicated that the lower‐energy excited electronic states of all the monosulfide compounds investigated are of a molecular nature in which the 4s S and 3d S atomic orbitals of sulfur play particularly dominant but by no means exclusive roles. The lower‐energy excited states of the molecules R2S n , n=2, 3, and 4, also contain significant 4s and 3d character; additionally, however, they are of S–S antibonding nature.

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