Discovery, Synthesis, and Characterization of an Isomeric Coordination Polymer with Pillared Kagome Net Topology
- 1 May 2007
- journal article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 46 (11) , 4371-4373
- https://doi.org/10.1021/ic070036t
Abstract
A topological isomer based on Zn2 paddlewheel, dicarboxylate, and diamine ligands is synthesized by solvothermal methods after careful modulation of the reaction conditions. The new framework is characterized by a pillared Kagome net topology and possesses a sustainable pore structure with high surface area (∼2400 m2/g) and large hexagonal channels (∼15 Å).Keywords
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