Spin-polarized (CIDEP) neutral α-aminoalkyl radicals from tertiary amines observed in solution by flash-photolysis electron spin resonance
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 2,p. 275-279
- https://doi.org/10.1039/p29840000275
Abstract
Laser flash photolysis of benzene-1,2:4,5-tetracarboxylic dianhydride in the presence of tertiary amines yielded α-aminoalkyl radicals, many of which had not been observed previously in solution. They were produced in a spin-polarized state via the Triplet Mechanism, to facilitate their observation by e.s.r.Keywords
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