Manganese porphyrins supported on montmorillonite as hydrocarbon mono-oxygenation catalysts: particular efficacy for linear alkane hydroxylation
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1365-1367
- https://doi.org/10.1039/c39900001365
Abstract
A supported Mn–porphyrin catalyst has been prepared by immobilisation of the tetracationic Mn [meso-tetra (4-N-methylpyridiniumyl)porphyrin]Cl4+ on montmorillonite, and is found to be efficient for alkene epoxidation and alkane hydroxylation by PhlO, with a higher ability to oxidize alkanes, and in particular short linear alkanes, than corresponding homogeneous or silica-supported Mn–porphyrin catalysts.Keywords
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