Synthesis and characterization of mono(carbene) complexes of copper and crystal structure of a linear thiazolinylidene compound
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 2,p. 313-316
- https://doi.org/10.1039/dt9950000313
Abstract
A series of neutral copper(I) mono(carbene) complexes was synthesized by the alkylation of thiazolyl or imidazolyl-cuprates. The cuprates were prepared from CuCl or Cul and 4-methylthiazolyl-, benzothiazol-2-yl-, 1-methylimidazolyl- or 1-methylbenzoimidazol-2-yl-lithium. The crystal structure of [CuCl{[graphic omitted]}] has been determined and shows a linear, monomeric thiazolinylidene copper chloride complex with a copper–carbene carbon bond length of 1.868(6)Å.Keywords
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