Synthesis of Enantiomerically Enriched α-Sulfenylated Ketones and Aldehydes
- 1 January 1987
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1987 (02) , 159-161
- https://doi.org/10.1055/s-1987-27870
Abstract
α-Sulfenylated carbonyl compounds are prepared by the reaction of imines of aldehydes and ketones containing α-hydrogens with disulfides via the metalloenamines. With (R)-α-phenylethylamine as chiral auxiliary, enantiomeric excesses of 13-51% are observed.Keywords
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