Acyclic 1,2-Induction in Radical Reactions: The Importance of Allylic Strain Effects
- 1 January 1991
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1991 (06) , 425-427
- https://doi.org/10.1055/s-1991-20751
Abstract
The stereoselectivity of hydrogen abstraction by ester-substituted radical 1 [XCH(R2)C????-(R1)CO2R] is explained by allylic strain effects. The ratio of threo:erythro products 2:3 depends upon the size of substituents X and R2.Keywords
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