Studies on steroids. Part 37. Synthesis of the four stereoisomers of 20,22-epoxycholesterol
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 19,p. 2116-2120
- https://doi.org/10.1039/p19760002116
Abstract
All four stereoisomers of 20,22-epoxycholesterol were synthesized from (20E)-cholesta-5,20(22)-dien-3β-ol. The configurational assignments were based on the analogy with the corresponding 5,6-dihydro-derivatives, prepared by stereochemically unequivocal routes.This publication has 1 reference indexed in Scilit:
- Cholesterol 20,22-epoxides: No conversion to pregnenolone by adrenal cytochrome P-450sccBiochemical and Biophysical Research Communications, 1976