Carbonyl intra-exchange in hexa- and hepta-rhodium carbonyl clusters
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 523-524
- https://doi.org/10.1039/c39750000523
Abstract
13 C n.m.r. studies on the three structurally related carbonyl clusters [Rh6(CO)16], [Rh6(CO)15]2– and [Rh7(CO)16]3– show that [Rh6(CO)16] is not fluxional at +70°, [Rh6(CO)15]2– readily undergoes intra-carbonyl exchange at –70° and [Rh7(CO)16]3– is not fluxional at –70° but undergoes partial intra-exchange at +25°.Keywords
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