SPECTRAL AND CHEMICAL PROPERTIES OF β- AND γ-FUNCTIONAL SILANES
- 1 February 1964
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 42 (2) , 298-304
- https://doi.org/10.1139/v64-048
Abstract
The synthesis of β- and γ-hydroxy- and keto-silanes is described, together with that of their carbon analogues. Unlike the α-isomers, the hydroxysilanes do not rearrange to silyl ethers, and the ultraviolet spectra of the silyl ketones is essentially the same as those of the carbon analogues, and unlike that of α-silyl ketones.β-Silyl ketones have a carbonyl-stretching frequency midway between that of ordinary ketones and α-silyl ketones. These effects are discussed.Keywords
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