Zirconocene-Mediated Intermolecular Coupling of One Molecule of Si-Tethered Diyne with Three Molecules of Organonitriles: One-Pot Formation of Pyrrolo[3,2-c]pyridine Derivatives via Cleavage of C⋮N Triple Bonds of Organonitriles
- 19 May 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (23) , 7172-7173
- https://doi.org/10.1021/ja0497173
Abstract
One Si-tethered diyne is coupled in one pot with three molecules of organonitriles promoted by a low-valent zirconocene species. Cleavage of one of the three C⋮N triple bonds and cleavage of the two Si−C bonds take place to afford pyrrolo[3,2-c]pyridine derivatives after hydrolysis.Keywords
This publication has 1 reference indexed in Scilit:
- Methane and benzene activation via transient (tert-Bu3SiNH)2Zr:NSi-tert-Bu3Journal of the American Chemical Society, 1988